Structure of a discrete dichloride hexahydrate cube as a tris(diisopropylamino)cyclopropenium salt.
نویسندگان
چکیده
منابع مشابه
Unexpected formation and crystal structure of tetrakis(1H-pyrazole-κN 2)palladium(II) dichloride
The title salt, [Pd(C3H4N2)4]Cl2, was obtained unexpectedly by the reaction of palladium(II) dichloride with equimolar amounts of 1-chloro-1-nitro-2,2,2-tris-(pyrazol-yl)ethane in methanol solution. The Pd(2+) cation is located on an inversion centre and has a square-planar coordination sphere defined by four N atoms of four neutral pyrazole ligands. The average Pd-N distance is 2.000 (2) Å. Th...
متن کاملEfficient synthesis of β-hydroxy thiocyanates from epoxides and ammonium thiocyanate using 1,4-bis(triphenylphosphonium)-2-butene dichloride as a new catalyst
1,4-bis(triphenylphosphonium)-2-butene dichloride was developed as a new phase transfer catalyst. This quaternized phosphonium salt catalyzed the regioselective ring opening of epoxides by thiocyanate ion to give β-hydroxy thiocyanates in high yields under mild conditions.
متن کاملTris(2-methylpiperidinium) tetrachloridoferrate dichloride
The asymmetric unit of the title salt, (C(6)H(14)N)(3)[FeCl(4)]Cl(2), consists of a tetra-hedral tetra-chloro-ferrate anion, three independent 2-methyl-piperidinium cations and two chloride ions. All the piperidine rings adopt chair conformations. In the crystal, the organic cations and the free chloride anions are linked into chains parallel to the a axis by N-H⋯Cl hydrogen bonds.
متن کاملNumerical Study of Reynolds Number Effects on Flow over a Wall-Mounted Cube in a Channel Using LES
Turbulent flow over wall-mounted cube in a channel was investigated numerically using Large Eddy Simulation. The Selective Structure Function model was used to determine eddy viscosity that appeared in the subgrid scale stress terms in momentum equations. Studies were carried out for the flows with Reynolds number ranging from 1000 to 40000. To evaluate the computational results, data was compa...
متن کاملTris(dialkylamino)aluminums: Syntheses, characterization, volatility comparison, and atomic layer deposition of alumina thin films
The syntheses and characterization of both tris(diethylamino)aluminum and tris(diisopropylamino)aluminum are presented in this letter. Characterization includes vapor pressure measurements and comparison of the two non-pyrophoric precursors showing them to be viable alternatives to trimethylaluminum. Ultimately, tris(diisopropyl)aluminum was successful in the atomic layer deposition of alumina ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Angewandte Chemie
دوره 45 45 شماره
صفحات -
تاریخ انتشار 2006